Researchers pertaining to both academia and industry have shown strong interest in developing and improving the existing critical ITS solutions. In some of the existing solutions, specially the ones that aim at providing context aware services, the knowledge of relative positioning of one node by other nodes becomes crucial. In this paper we explore, apart from the conventional use of GPS data, the applicability of image processing to aid in determining the relative positions of nodes in a vehicular network. Experiments conducted show that both the use of location information and image processing works well and can be deployed depending on the requirement of the application. Our experiments show that the results that used location information were affected by GPS errors, while the use of image processing, although producing more accurate results, require significantly more processing power.